Global warming potential (GWP) of HFC refrigerants

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Global warming potential (GWP) of HFC refrigerants

2024-06-16 14:34| 来源: 网络整理| 查看: 265

Global warming potential (GWP) definition

 

The Global warming potential (GWP) is the metric most commonly used to indicate the climate impact potential of a refrigerant emission. [1] According to UNEP, GWP can be defined as a measure of the relative global warming effects of different gases (in this case, refrigerants). It assigns a value to the amount of heat trapped by a certain mass of a refrigerant relative to the amount of heat trapped by the same mass of carbon dioxide over a specific period of time.[2] Carbon dioxide was chosen by the Intergovernmental Panel on Climate Change (IPCC) as the reference gas and its GWP is equal to 1.

 

Consistent with the Kigali Amendment, the IIR uses GWP values for the 100-year timeframe in its publications.[3] The 100-year GWP is more commonly used in scientific articles, standards, and regulations, which is helpful for an efficient discussion of the climate impact.[1] Some experts advocate the use of GWP values with shorter integration time horizons, particularly in the case of HFCs which often have relatively short lifetimes. Indeed, a 20-year time horizon is more relevant when discussing climate change during the next few decades, where it may also be better in differentiating between substances with shorter lifetimes.[1]

 

100-year and 20-year GWP values of HFC-based refrigerants

 

The table below presents 100-year GWP and 20-year GWP values for HFC refrigerants. We listed blends that include at least one HFC in their composition. This means that our table also include HFC/HFO blends or HFC/hydrocarbons blends.

The values were extracted from UNEP’s RTOC 2022 report, in which GWP values have been updated according to the World Meteorological Organization (WMO, 2022). In previous reports, namely UNEP’s RTOC 2018 report and UNEP’s TEAP 2021 report, GWP values were sourced from WMO 2019 and the Intergovernmental Panel on Climate Change (IPCC) sixth assessment report, 2021 (AR6).

 

 

Refrigerant designation Type Blend composition Safety Class GWP 100 years GWP 20 years R125 HFC Single-component   A1 3 820 6 790 R134a HFC Single-component   A1 1 470 4 060 R143a HFC Single-component   A2L 5 900 7 900 R152a HFC Single-component   A2 153 550 R23 HFC Single-component   A1 14 700 12 400 R227ea HFC Single-component   A1 3 580 5 830 R236fa HFC Single-component   A1 9 120 7 820 R245fa HFC Single-component   B1 966 3 190 R32 HFC Single-component   A2L 749 2 620 R41 HFC Single-component     137 492 R404A blend R-125/143a/134a A1 4 808 7 258 R407A blend R-32/125/134a A1 2 266 4 864 R407B blend R-32/125/134a A1 3 043 5 827 R407C blend R-32/125/134a A1 1 892 4 411 R407D blend R-32/125/134a A1 1 714 4 254 R407E blend R-32/125/134a A1 1 642 4 110 R407F blend R-32/125/134a A1 1 959 4 447 R407G blend R-32/125/134a A1 1 511 4 092 R407H blend R-32/125/134a A1 1 588 4 002 R407I blend R-32/125/134a A1 1 529 4 011 R410A blend R-32/125 A1 2 285 4 705 R410B blend R-32/125 A1 2 438 4 914 R413A blend R-218/134a/600a A2 2 149 4 196 R417A blend R-125/134a/600 A1 2 515 5 194 R417B blend R-125/134a/600 A1 3 287 6 107 R417C blend R-125/134a/600 A1 1 903 4 523 R419A blend R-125/134a/E170 A2 3 221 6 000 R419B blend R-125/134a/E170 A2 2 558 5 242 R421A blend R-125/134a A1 2 833 5 643 R421B blend R-125/134a A1 3 468 6 381 R422A blend R-125/134a/600a A1 3 420 6 245 R422B blend R-125/134a/600a A1 2 718 5 440 R422C blend R-125/134a/600a A1 3 353 6 177 R422D blend R-125/134a/600a A1 2 950 5 699 R422E blend R-125/134a/600a A1 2 793 5 534 R423A blend R134a/227ea A1 2 472 4 901 R424A blend R-125/134a/600a/600/601a A1 2 620 5 337 R425A blend R-32/134a/227ea A1 1 590 4 006 R426A blend R-125/134a/600/601a A1 1 562 4 122 R427A blend R-32/125/143a/134a A1 2 392 4 911 R427B blend R-32/125/143a/134a A1 2 765 5 192 R427C blend R-32/125/143a/134a A1 2 320 4 767 R428A blend R-125/143a/290/600a A1 4 141 6 842 R429A blend R-E170/152a/600a A3 16 56 R430A blend R-152a/600a A3 117 418 R431A blend R-290/152a A3 45 160 R434A blend R-125/143a/134a/600a A1 3711 6 363 R435A blend R-E170/152a A3 31 111 R437A blend R-125/134a/600/601 A1 1 899 4 511 R438A blend R-32/125/134a/600/601a A1 2 432 5 073 R439A blend R-32/125/600a A2 2 170 4 501 R440A blend R-290/134a/152a A2 173 603 R442A blend R-32/125/134a/152a/227ea A1 2 041 4 443 R444A blend R-32/152a/1234ze(E) A2L 98 346 R444B blend R-32/1234ze(E)/152a A2L 327 1 145 R445A blend R-744/134a/1234ze(E) A2L 133 370 R446A blend R-32/1234ze(E)/600 A2L 510 1 783 R447A blend R-32/125/1234ze( E) A2L 643 2021 R447B blend R-32/125/1234ze(E) A2L 815 2 326 R448A blend R-32/125/1234yf/134a /1234ze(E) A1 1 497 3 300 R448B blend R-32/125/1234yf/134a/1234ze€ A1 1 415 3 235 R449A blend R-32/125/1234yf/134a A1 1 504 3 358 R449B blend R-32/125/1234yf/134a A1 1 519 3 419 R449C blend R-32/125/1234yf/134a A1 1 340 3 060 R450A blend R-1234ze(E)/134a A1 618 1 708 R451A blend R-1234yf/134a A2L 151 416 R451B blend R-1234yf/134a A2L 166 456 R452A blend R-1234yf/32/125 A1 2 336 4 295 R452B blend R-32/125/1234yf A2L 769 2 231 R452C blend R-32/125/1234yf A1 2 424 4 470 R453A blend R-32/125/134a/227ea/600/601a A1 1 884 4 358 R454A blend R-32/1234yf A2L 263 918 R454B blend R-32/1234yf A2L 516 1 806 R454C blend R-32/1234yf A2L 162 565 R455A blend R-744/32/1234yf A2L 162 565 R456A blend R-32/134a/1234ze(E) A1 707 1 987 R457A blend R-32/1234yf/152a A2L 154 539 R457B blend R-32/1234yf/152a A2L 278 973 R457C blend R-32/1234yf/152a A2L 79 278 R458A blend R-32/125/134a/227ea/236fa A1 1 747 4 136 R459A blend R-32/1234yf/1234ze(E) A2L 510 1 782 R459B blend R-32/1234yf/1234ze(E) A2L 158 552 R460A blend R-32/125/134a/1234ze( E) A1 2 282 4 415 R460B blend R-32/125/134a/1234ze(E) A1 1 459 3 244 R460C blend R-32/125/134a/1234ze(E) A1 791 2 105 R461A blend R-125/143a/134a/227ea/600a A1 3 045 5 720 R462A blend R-32/125/143a/134a/600 A2 2 437 5 032 R463A blend R-744/32/125/1234yf/134a A1 1 622 3 549 R464A blend R-32/125/1234ze(E)/227ea A1 1 449 2 893 R465A blend R-32/290/1234yf A2 158 552 R466A blend R-32/125/13I1 A1 807 2 065 R467A blend R-32/125/134a/600a A1 1 420 3 855 R468A blend R-1132a/32/1234yf A2L 162 565 R468B blend R-1132a/32/1234yf A2L 98 342 R468C blend R-1132a/32/1234yf A2L 315 1102 R469A blend R-744/HFC- 32/HFC-125 A2L 1 485 3 059 R470A blend R-744/32/HFC-125/HFC-134a/HFO-1234ze(E)/HFC-227ea A1 1 064 2 197 R470B blend R-744/HFC-32/HFC-125/HFC-134a/HFO-1234ze(E)/HFC-227ea A1 821 1 615 R471A blend R-1234ze(E)/227ea/1336mzz( E) A1 159 271 R472A blend R-744/HFC-32/HFC-134a A1 370 1 086 R472B blend R-744/32/134a A1 546 1 562 R473A blend R-1132a/23/744/125 A1 1 853 1 920 R503 blend R-23/13 A1 15 658 12 400 R507A blend R-125/143a A1 4 860 7 345 R508A blend R-23/116 A1 13 419 10 350 R508B blend R-23/116 A1 13 566 10 586 R512A blend R-134a/152a A2 219 726 R513A blend R-1234yf/134a A1 647 1 788 R513B blend R-1234yf/134a A1 611 1 686 R515B blend R-1234ze( E)/227ea A1 320 523

 

 

Useful links for further information

 

UNEP/ASHRAE. Update on New Refrigerants Designations and Safety Classifications April 2023.https://iifiir.org/en/fridoc/update-on-new-refrigerants-designations-and-safety-classifications-2023-147209 UNEP. (2023). Refrigeration, Air Conditioning and Heat Pumps Technical Options Committee (RTOC) 2022 Assessment Report (Montreal Protocol on Substances That Deplete the Ozone Layer.). https://iifiir.org/en/fridoc/montreal-protocol-on-substances-that-deplete-the-ozone-layer-2022-146932

 

 

Acknowledgements

 

This document was prepared by Monique Baha (IIR Scientific and Technical Information Department) and proofread by Maud Grasmenil, under the supervision of Jean-Luc Dupont (Head of the Scientific and Technical Information Department).

 

 

References

[1] UNEP. (2023). Refrigeration, Air Conditioning and Heat Pumps Technical Options Committee (RTOC) 2022 Assessment Report (Montreal Protocol on Substances That Deplete the Ozone Layer.). https://ozone.unep.org/system/files/documents/RTOC-assessment%20-report-2022.pdf

[2] UNEP. (2016). Global Warming Potential (GWP) of Refrigerants: Why are Particular Values Used? https://wedocs.unep.org/xmlui/handle/20.500.11822/28246

[3] Domanski, P., & Motta, S. Y. (2022). Low-GWP Refrigerants: Status and Outlook. 48th Informatory Note on Refrigeration Technologies. IIF-IIR. https://doi.org/10.18462/iif.NItec48.06.2022



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